Did you measure this with the batteries still connected to the UPS? Or, did you lift one of the legs from the charger so you were actually seeing the batteries' voltage? (ideally, you'd put a brief load on the battery pack to remove any surface charge before measuring).
Float charging a battery should leave you with ~2.3 volts per cell (6 cells in a nominal 12V battery means 13.8V per battery or 27.6V for the entire battery pack). Even a fast charge would typically only be about 2.4 - 2.45V/cell (or 28.2 - 29.4V for the pack). Are you using a DMM that is reasonably calibrated?
It is not uncommon for UPS's to overcharge their battery packs. The batteries you removed reflect the common result of such a "cooking". You should check your UPS to see what sort of float voltage it impresses on the battery pack.
I have each of my UPSs set up to log mains voltage/current, load voltage/current, battery voltage, temperature, etc. regularly (once a minute) and dump these log files onto one of my servers. This lets me see if something wonky is happening in the UPSs before things go off the rails (I have a little script that watches the log files and alerts me of any trends that seem odd). I tend to see ~13.6V reported for each 12V "battery" in a battery pack (again, some packs have 4 such batteries so ~55V for the pack).
Another Q: can 2 batteries at different discharge level be charged together by the UPS as a pack? Like one is at 14V, and another at 6V, but surprisingly keeps charging? How in this case the charge levels between batteries, and how the UPS decides that the pack get fully charged? How generally the UPS measures a battery charge level?
But, battery management systems (BMS) are an expensive addition to what is typically a commodity product (UPS). OTOH, you'll note that an electric car invests a fair bit in its BMS as the battery is something that has significant value and premature failure would tarnish the car maker's image in the market!
Note that even many of the larger UPSs don't go beyond treating a battery pack as just a monolithic "big battery". E.g., several of my UPSs use a 48V battery pack but still see it as a "2 terminal device" (i.e., like a single "battery")
Bottom line, you want to put two batteries of roughly equivalent "condition" into the UPS (i.e., never replace just one!)
More Q: can I use together a 3-year old good battery and a brand new one as a pack? If not recommended - why?
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